Okay so I tried to swap the RAM and having only one in allowed me more time to see what the issue is.
I had enough time to install SpeedFan, and I got this:
http://img300.imageshack.us/img300/3216/speedfansg2.th.pnghttp://img300.imageshack.us/images/thpix.gif
I believe I have discovered from being in close proximity that Temp3 to be the Intel NVIDIA nForce chipset where the copper heat pipe is (*Please note that the copper heat pipes in the RAM slots are not used in my build*):
http://images.tigerdirect.ca/itemDetails/A455-2404/A455-2404-out2-hl.jpg
I discovered this after taking out one of the video cards located in the PCIe slot located closest to the chip. The temperature seems to stay around that # in the SS with or without the card installed. However. When I start up a game WITH the second video card in it shuts down. When I boot up a game WITHOUT the second video card it stays on and I can continue to use it and it functions normally, albeit without the performance from the missing video card. The temperature remains the same though, at about ~83c.
When I go home I will swap out video cards from the lower PCIe slot to make sure that both video cards are fine. That way I can eliminate an issue with the graphics cards
Now I'm a bit puzzled as to how the chipset overheating could become an issue. From the evidence am I coming to the right conclusion? I really have never come across this issue before. I've asked my bro to check his temps using the same program, since he has an identical MOBO with a similar setup to mine. I'm waiting to hear back from him shortly.